Scaled‐up, selective and green synthesis of sulfoxides under mild conditions using (CeIII‐MoVI)Ox/aniline hybrid rods as an efficient catalyst

نویسندگانsadeq malakooti
نشریهApplied Organometallic Chemistry
شماره صفحات1-11
شماره سریال23
شماره مجلد12
ضریب تاثیر (IF)2.319
نوع مقالهFull Paper
تاریخ انتشار2019
رتبه نشریهISI
نوع نشریهالکترونیکی
کشور محل چاپایران
نمایه نشریهJCR،Scopus

چکیده مقاله

A novel hybrid material, (CeIII‐MoVI)Ox/aniline, with rod‐like morphology is synthesized through a wet chemical method using Mo3O10(C6H5NH3)2.2H2O nanowires as precursor. The synthesized materials are characterized by XRD, XPS, SEM, TEM, FTIR, Raman, UV–Vis, TGA, and elemental analysis. Also, their catalytic activities as a hybrid catalyst are tested in the selective oxidation of sulfides using hydrogen peroxide as a green oxidant. The proposed novel hybrid catalyst shows an excellent performance under green conditions at mild temperature. Furthermore, the scalability of the oxidation reaction is shown by making multi‐gram quantities at optimized conditions.

لینک ثابت مقاله

tags: cerium‐molybdenum oxide rods, organic–inorganic hybrid ,sulfide oxidation