| Authors | Alireza Farrokhi,Jose´ Miguel Sansano |
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| Journal | New Journal of Chemistry |
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| Page number | 19963-19976 |
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| Serial number | 45 |
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| Volume number | 42 |
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| IF | 3.269 |
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| Paper Type | Full Paper |
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| Published At | 2021 |
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| Journal Grade | ISI |
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| Journal Type | Electronic |
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| Journal Country | Iran, Islamic Republic Of |
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| Journal Index | JCR،Scopus |
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Abstract
A metal–organic framework functionalized with a cobalt-complex is prepared via post-synthetic modification of Fe-MIL-101-NH2. Initially, Fe-MIL-101-NH2 reacted with isatin to produce Fe-MIL-101-isatin-Schiff-base, which can anchor the cobalt by the addition of cobalt acetate. The resulting MOF-Co catalyst is characterized by employing multiple techniques. This new modified MOF acts as a heterogeneous and recyclable catalyst for efficient Ullmann, Buchwald–Hartwig, Hirao, Hiyama and Mizoroki–Heck cross-coupling reactions of several aryl halides/phenylboronic acid/phenyltosylate with phenols, anilines/heterocyclic amines, triethyl phosphite, triethoxyphenylsilane and alkenes and generates the expected coupling products in good to high yields.
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