| Authors | ,Maasoumeh Jafarpour, , |
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| Journal | Bioorganic & Medicinal Chemistry |
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| Page number | 3097-3101 |
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| Serial number | 15 |
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| Volume number | 8 |
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| IF | 3.075 |
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| Paper Type | Full Paper |
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| Published At | 2007 |
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| Journal Grade | ISI |
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| Journal Type | Typographic |
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| Journal Country | Iran, Islamic Republic Of |
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| Journal Index | ISI،JCR،Scopus |
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| Keywords | Alcohol; Aldehyde; Ketone; Oxidation; Tetrabutylammonium peroxymonosulfate; Mn, porphyrin |
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Abstract
A novel biomimetic method for rapid oxidation of a wide range of benzylic, allylic, aliphatic, primary and secondary
alcohols to the related aldehydes and ketones using Bu4NHSO5 catalyzed by Mn(TPP)OAc/pyridine system with high to excellent
yields and excellent selectivity has been developed. The high turnover rates obtained in this catalytic system represent a high efficiency and also relative stability of Mn-porphyrin catalyst towards oxidative degradation. The presence of an electron-withdrawing
group on the phenyl ring of both benzyl alcohol and porphyrin ligand increases the reactivity of substrate as well as catalytic activity
of Mn-porphyrin catalyst in the oxidation reaction
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