Optimization of COD removal of raw landfill leachate using the magnetic graphene oxide/WO3 nanocomposite: Isotherms, kinetics, and thermodynamics studies

Abstract

ABSTRACT Landfill leachate is the fluid percolating through the landfill and is one of the most important environmental challenges that lead to the contamination of water and soil resources. In this study, magnetic graphene oxide nanoparticles with WO3 (GO-Fe3O4/WO3) were synthesized through the hydrothermal method to eliminate chemical oxygen demand (COD) from leachate. The obtained products were characterized using X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), Thermogravimetric analysis (TGA), and Vibrating sample magnetometer (VSM) analysis. The influence of various operating parameters, such as initial solution pH, adsorbent dosage, contact time, and temperature, on COD removal was studied. Additionally, kinetic, isotherm and thermodynamic studies were conducted to evaluate the adsorption capacity of the adsorbent. The results revealed that the maximum adsorption capacity of GO-Fe3O4/WO3 was 2500 mg/g adsorbent at pH 4, a contact time of 90 minutes, an adsorbent dosage of 25 mg g-1, and a temperature below 298 K, respectively. According to the adsorption kinetic fitting results, the experimental adsorption data were well described by the pseudo-second-order kinetic with an R2 value of 0.97, and the Freundlich isotherm equation with an R2 value of 0.99. The thermodynamic results indicated that the adsorption was spontaneous and exothermic for COD adsorption. In general, the adsorption process of the synthesized GO-Fe3O4/WO3 nanocomposite revealed that it is highly effective for landfill leachate treatment and has great practical value in leachate treatment.