Authors | Mohammad ali Nasseri,Ali Allahresani |
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Journal | Applied Organometallic Chemistry |
Page number | 4809-4820 |
Serial number | 33 |
Volume number | 6 |
IF | 2.319 |
Paper Type | Full Paper |
Published At | 2019 |
Journal Grade | ISI |
Journal Type | Typographic |
Journal Country | Iran, Islamic Republic Of |
Journal Index | JCR،Scopus |
Abstract
In the presence of cobalt (III) salen complex, selective oxidation of alcohols to carbonyl compounds was studied by molecular oxygen using isobutyraldehyde as an oxygen acceptor. The effect of cobalt (III) salen complex in the oxidation reaction was studied, and the results showed that Co (III) salen complex is very active and selective in the oxidation of various alcohols. Also, the effect of important factors including catalyst amount, solvent and temperature was investigated on the reaction. Furthermore, the catalytic activities of CoFe2O4@SiO2‐supported Schiff base metal complex as well as the effect of molecular oxygen (O2) as a green oxidant were studied. The results showed that benzaldehyde was the major product and the heterogeneous catalyst was highly reusable.
tags: benzyl alcohol, Co (III) salen complex, isobutyraldehyde, oxidation