Authors | Mohammad ali Nasseri,,Ali Allahresani,Oliver Reiser |
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Journal | Journal of Hazardous Materials |
Page number | 10-32 |
Serial number | 400 |
IF | 3.925 |
Paper Type | Full Paper |
Published At | 2020 |
Journal Grade | ISI |
Journal Type | Typographic |
Journal Country | Netherlands |
Journal Index | JCR،Scopus |
Abstract
A green protocol has been developed for preparation of the wide variety of colored xanthene derivatives using a new efficient magnetic solid acid catalyst bearing polyamidoamine dendrimer moiety as a nanoscopic compound. Dendrimers, highly symmetric molecules around a core and 3D spherical morphology, show interesting traits based on their functionalized groups on the branched surface. They can be designed to provide water soluble structures or pseudo-active sites of biomolecules. The catalyst was assembled via a polyamidoamine dendrimer immobilized on the surface of γ-Fe2O3 followed by the sulfonylation of the amine groups by chlorosulfonic acid resulting in γ-Fe2O3@PAMAM-SO3H. Herein, PAMAM dendrimer with repeating amine/amide branches as catchable sites of sulfonic acid groups was introduced as transformer of homogeneous to heterogeneous acidic catalysts. The physicochemical properties of synthesized catalyst were studied using by FT-IR, FE-SEM, XRD, VSM, EDS, TGA/DTG, and TEM. Finally, the catalytic activity of γ-Fe2O3@PAMAM-SO3H was evaluated for the preparation of xanthene derivatives via a one-pot, three components reaction of aromatic aldehydes with i) β-naphthol, ii) cyclic 1,3-dicarbonyl, iii) β-naphthol and cyclic 1,3-dicarbonyl compounds, iv) 2-hydroxy-1,4-naphthoquinone, leading to the eco-riendly preparation of the target compounds in good to excellent yields. The catalyst could be easily recycled for at least five consecutive runs without significant loss in its catalytic activity.
tags: γ-Fe2O3@PAMAM-SO3HSolid acid magnetic catalystXanthene colored derivativesEco-friendly