Synthesis of CuO/Bi2O3 nanocomposite for efficient and recycling photodegradation of methylene blue dye

AuthorsMohammad Hossein Sayadi,Mahmood Hajiani,MohammadReza Rezaei
JournalInternational Journal of Environmental Analytical Chemistry
Page number7165-7178
Serial number102
Volume number18
IF1.208
Paper TypeFull Paper
Published At2020
Journal GradeISI
Journal TypeElectronic
Journal CountryIran, Islamic Republic Of
Journal IndexJCR،Scopus

Abstract

Dyes are considered as the most important pollutants in water because of their applications and potential risks for living organisms. Therefore, in this study, the efficiency of CuO/Bi2O3 nanocomposite for photocatalytic degradation of methylene blue dye in aqueous solutions under UV-C irradiation was investigated. The CuO/Bi2O3 nanocomposite was prepared and then the nanoparticles were characterised using X-ray diffraction (XRD), Scanning Electron Microscopy (FESEM), Fourier Infrared Spectroscopy (FTIR), Thermal stability analysis (TGA) and plasma atomic emission spectroscopy (ICP-OES). The effect of various parameters such as pH (3,5,7,9 and 11), catalyst dosage (0.1, 0.2, 0.3, 0.5 g/L) and methylene blue dye concentration (10, 20, 30, 40 and 50 mg/l) was evaluated. Finally, the concentration of dye was measured using a spectrophotometer. FESEM images showed that the nanoparticles were below 100 nm. The results of this survey showed that dye degradation was higher at acidic pH and catalyst content of 0.2 g/l (87.76%) and also decreased with increasing initial dye concentration. The photocatalytic reaction followed pseudo-first-order kinetics. This photocatalyst also showed good stability after 4 periods of reuse. Therefore, it can be concluded that the CuO/Bi2O3 catalyst has the swell potential for application in colour removal from wastewater due to its high efficiency and low cost.

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tags: Photocatalyst; sol-gel; Cuo/ Bi2O3 catalysts; methylene blue dye; UV-C light