Authors | José Miguel Sansano |
---|---|
Journal | RSC Advances |
Page number | 19121-19127 |
Serial number | 11 |
Volume number | 31 |
Paper Type | Full Paper |
Published At | 2021 |
Journal Grade | ISI |
Journal Type | Electronic |
Journal Country | Iran, Islamic Republic Of |
Journal Index | ISI،JCR،Scopus |
Abstract
A direct imination reaction was developed by tandem reaction of alcohols and nitro compounds in the presence of Cu-isatin Schiff base--Fe2O3 as a nanomagnetically recyclable catalyst under solvent-free conditions. By this method, various imines were prepared in good to high yields from one-pot reaction of various alcohols (primary aromatic and aliphatic) and nitro compounds (aromatic and aliphatic) via auto-hydrogen transfer reaction. Use of an inexpensive and easily reusable catalyst, without requiring any additives or excess amounts of benzyl alcohol as the reaction solvent are the other advantageous of this method. This catalytic system has the merits of cost effectiveness, environmental benignity, excellent recyclability and good reproducibility.
tags: nanomagnet, tandem, heterogeneous